KMID : 0380319740130000063
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Journal of Korean Research Institute for Better Living 1974 Volume.13 No. 0 p.63 ~ p.69
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The Kinetics and Mechanisms of Nucieophilic Hydrolysis of ¥ø-nitro-2-vinyl thiophene(NVT)
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Abstract
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The rats constants of the nucleophilic hudrolysis of ¥ø-nitro-2-vinyl thiophene (NVT) were determined at vrious pH and the rate equations were obtained that can be applied to the whole range of pH.
From these rate equations, the mechanisms of the reaction are different in acidic and basic media.
The reaction of hydrolysis in acid media is started by the addition of the hydroxide ion.
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